| dc.creator |
Labban, Abdul K. |
|
| dc.creator |
López de la Fuente, F. L. |
|
| dc.creator |
Rodríguez Cheda, José A. |
|
| dc.creator |
Westrum, Edgar F. |
|
| dc.creator |
Fernández Martín, Fernando |
|
| dc.date |
2007-12-26T12:12:23Z |
|
| dc.date |
2007-12-26T12:12:23Z |
|
| dc.date |
1989-04 |
|
| dc.date.accessioned |
2017-01-31T00:59:31Z |
|
| dc.date.available |
2017-01-31T00:59:31Z |
|
| dc.identifier |
The Journal of Chemical Thermodynamics 21(4): 375-384. |
|
| dc.identifier |
<http://hdl.handle.net/2027.42/28189> |
|
| dc.identifier |
http://www.sciencedirect.com/science/article/B6WHM-4CRHC6N-X9/2/749b801d3eef652f7417a6578f7d641e |
|
| dc.identifier |
http://hdl.handle.net/10261/2603 |
|
| dc.identifier |
10.1016/0021-9614(89)90138-9 |
|
| dc.identifier.uri |
http://dspace.mediu.edu.my:8181/xmlui/handle/2027 |
|
| dc.description |
The heat capacity of thallium(I) n-heptanoate has been remeasured on a new sample on which the preparative procedures were modified to eliminate the 1-1 (salt+acid) complex (soap) in a previously studied sample. The sub-ambient heat capacity of a new highly pure thallium(I) n-heptanoate is characterized by one set of transitions between 262 and 272 K and another transition at 301 K. The lowest transition temperature at 262.1 K has a maximum of Cp, m ~ 559R. Next, a bifurcated pair (at 268.6 and 271.4K) have Cp, m ~ 300R, and the highest transition (at 301.0 K) has a maximum Cp, m ~ 1697R. The corresponding values of ΔtrsSmo for the two sets are about 2.24R and 1.10R. At 298.15 K the values of Δ0TSmo, Δ0THmo, and Φmo(T) are 39.79R, 5979R·K, and 19.74R. Smoothed thermodynamic functions at selected temperatures are tabulated through melting. |
|
| dc.description |
Peer reviewed |
|
| dc.format |
598149 bytes |
|
| dc.format |
application/pdf |
|
| dc.language |
eng |
|
| dc.publisher |
Elsevier |
|
| dc.rights |
openAccess |
|
| dc.subject |
Chemical Thermodynamics |
|
| dc.subject |
Thalium alkanoates |
|
| dc.subject |
Thermophysics |
|
| dc.subject |
Heat Capacity |
|
| dc.title |
Thermodynamics of thallium alkanoates VI. Thallium(I) n-heptanoate revisited |
|
| dc.type |
Artículo |
|